Why Wicky can drive you Wacky
Originally Posted by wicky,Jul 24 2006, 09:13 PM
what did I do?
Some might view this as an example of the worst that could happen and proof that the system did eventually root out the misinformation.
I disagree. Something as blatantly wrong as this will be fixed sooner or later. What is more insidious are the negative slants and biased cherry picking of facts that can paint a quite inaccurate portrait of something or someone. This is as hard to fix as a flat tire in a blizzard. And if it does get fixed, it could change again five minutes hence.
Unfortunately, telling yourself that it really doesn't matter what Wikipedia says is not a realistic option anymore. Wikipedia is growing rapidly in its number of articles and users, and for many people Wikipedia will be the first and only source they'll see.
Originally Posted by The Raptor,Jul 25 2006, 03:18 AM
An Op-Ed article that Seigenthaler published in USA Today detailed his frustrating and failed attempts to track down the source of this statement. The perpetrator eventually came forward with an apology and an explanation that it had been a joke gone bad.
Some might view this as an example of the worst that could happen and proof that the system did eventually root out the misinformation.
I disagree. Something as blatantly wrong as this will be fixed sooner or later. What is more insidious are the negative slants and biased cherry picking of facts that can paint a quite inaccurate portrait of something or someone. This is as hard to fix as a flat tire in a blizzard. And if it does get fixed, it could change again five minutes hence.
Unfortunately, telling yourself that it really doesn't matter what Wikipedia says is not a realistic option anymore. Wikipedia is growing rapidly in its number of articles and users, and for many people Wikipedia will be the first and only source they'll see.

Some might view this as an example of the worst that could happen and proof that the system did eventually root out the misinformation.
I disagree. Something as blatantly wrong as this will be fixed sooner or later. What is more insidious are the negative slants and biased cherry picking of facts that can paint a quite inaccurate portrait of something or someone. This is as hard to fix as a flat tire in a blizzard. And if it does get fixed, it could change again five minutes hence.
Unfortunately, telling yourself that it really doesn't matter what Wikipedia says is not a realistic option anymore. Wikipedia is growing rapidly in its number of articles and users, and for many people Wikipedia will be the first and only source they'll see.

Originally Posted by wicky,Jul 25 2006, 12:49 PM
I don't know what that says, but it seems complicated and confusing.
The initial three point calibrations consisted of 20, 100 and 500 ul injections of the calibration solutions. A calibration factor on each analyte was generated using a best fit line method using the HP data system. If the r2 factor generated from this line was not greater than 0.990, an additional three point calibration would have been performed. Method detection limits were calculated to be 1.0 ug/L for the individual compounds.
TABLE 1
Dichlorodifluoromethane Carbon Tetrachloride Chloroethane
Trichlorofluoromethane 1,2-Dichloroethane Benzene
1,1-Dichloroethene Trichloroethene Toluene
Methylene Chloride 1,1,2-Trichloroethane Ethylbenzene
trans-1,2-Dichloroethene Tetrachloroethene m-/p-Xylene
1,1-Dichloroethane Chloroform o-Xylene
cis-1,2-Dichloroethene 1,1,1,2-Tetrachloroethane Vinyl Chloride
1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane Freon 113
4-Methyl-2-Pentanone Cyclohexane Acetone
Chlorobenzene 2-Butanone
Sample Replicates
A replicate analysis (duplicate) is run when concentrations exceed the calibrated range of the instrument/detector being used. The duplicate sample is diluted using a smaller injection volume to assure that the instrument response falls within 50% of the calibrated range. In addition, a duplicate analysis is run a minimum of once each day to evaluate the reproducibility of the sampling system and instrument. If the difference between samples varies more than 20%, the entire system is evaluated and the inconsistency is determined and corrected, if possible.
Equipment Blanks
Blanks are run at the beginning of each workday, after calibrations and whenever sampling conditions appear to change. New vapor probes are used following each sample with positive results or when probes were damaged during installation. The blanks are collected using an ambient air sample. These blanks checked the septum, syringe, GC column, GC detector and the ambient air. Contamination was not found in any of the blanks analyzed during this investigation. Blank results are given along with the sample results.
Originally Posted by The Raptor,Jul 25 2006, 01:02 PM
An initial 3-point calibration was performed on July 25, 2006 by preparing a calibration solution from a pre-mixed standard supplied by Supelco, Inc. The standard contained common halogenated solvents and aromatic hydrocarbons (see Table 1). The individual compound concentrations in the standards ranged between 0.025 ng/ul and 0.25 ng/ul.
The initial three point calibrations consisted of 20, 100 and 500 ul injections of the calibration solutions. A calibration factor on each analyte was generated using a best fit line method using the HP data system. If the r2 factor generated from this line was not greater than 0.990, an additional three point calibration would have been performed. Method detection limits were calculated to be 1.0 ug/L for the individual compounds.
TABLE 1
Dichlorodifluoromethane Carbon Tetrachloride Chloroethane
Trichlorofluoromethane 1,2-Dichloroethane Benzene
1,1-Dichloroethene Trichloroethene Toluene
Methylene Chloride 1,1,2-Trichloroethane Ethylbenzene
trans-1,2-Dichloroethene Tetrachloroethene m-/p-Xylene
1,1-Dichloroethane Chloroform o-Xylene
cis-1,2-Dichloroethene 1,1,1,2-Tetrachloroethane Vinyl Chloride
1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane Freon 113
4-Methyl-2-Pentanone Cyclohexane Acetone
Chlorobenzene 2-Butanone
Sample Replicates
A replicate analysis (duplicate) is run when concentrations exceed the calibrated range of the instrument/detector being used. The duplicate sample is diluted using a smaller injection volume to assure that the instrument response falls within 50% of the calibrated range. In addition, a duplicate analysis is run a minimum of once each day to evaluate the reproducibility of the sampling system and instrument. If the difference between samples varies more than 20%, the entire system is evaluated and the inconsistency is determined and corrected, if possible.
Equipment Blanks
Blanks are run at the beginning of each workday, after calibrations and whenever sampling conditions appear to change. New vapor probes are used following each sample with positive results or when probes were damaged during installation. The blanks are collected using an ambient air sample. These blanks checked the septum, syringe, GC column, GC detector and the ambient air. Contamination was not found in any of the blanks analyzed during this investigation. Blank results are given along with the sample results.

The initial three point calibrations consisted of 20, 100 and 500 ul injections of the calibration solutions. A calibration factor on each analyte was generated using a best fit line method using the HP data system. If the r2 factor generated from this line was not greater than 0.990, an additional three point calibration would have been performed. Method detection limits were calculated to be 1.0 ug/L for the individual compounds.
TABLE 1
Dichlorodifluoromethane Carbon Tetrachloride Chloroethane
Trichlorofluoromethane 1,2-Dichloroethane Benzene
1,1-Dichloroethene Trichloroethene Toluene
Methylene Chloride 1,1,2-Trichloroethane Ethylbenzene
trans-1,2-Dichloroethene Tetrachloroethene m-/p-Xylene
1,1-Dichloroethane Chloroform o-Xylene
cis-1,2-Dichloroethene 1,1,1,2-Tetrachloroethane Vinyl Chloride
1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane Freon 113
4-Methyl-2-Pentanone Cyclohexane Acetone
Chlorobenzene 2-Butanone
Sample Replicates
A replicate analysis (duplicate) is run when concentrations exceed the calibrated range of the instrument/detector being used. The duplicate sample is diluted using a smaller injection volume to assure that the instrument response falls within 50% of the calibrated range. In addition, a duplicate analysis is run a minimum of once each day to evaluate the reproducibility of the sampling system and instrument. If the difference between samples varies more than 20%, the entire system is evaluated and the inconsistency is determined and corrected, if possible.
Equipment Blanks
Blanks are run at the beginning of each workday, after calibrations and whenever sampling conditions appear to change. New vapor probes are used following each sample with positive results or when probes were damaged during installation. The blanks are collected using an ambient air sample. These blanks checked the septum, syringe, GC column, GC detector and the ambient air. Contamination was not found in any of the blanks analyzed during this investigation. Blank results are given along with the sample results.











