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I like the dark rims on the dark car (with the wheels filling out the wheel well as in the picture)...but have some more thoughts/questions for you...
If you are getting those wheels in 16"/17", I would consider lowering the car as a must...the dark on dark with lots of space around the tire probably doesn't look good to me. (Again, I like the after picture, but not sure how you get there)
At 18" (or lowered suspension) I think it looks real good.